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rdf:type
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Description
| - Treatment of the [2-Cp-9tBuNH-closo-2,1,7,9-FeC3B8H10] (1) ferratricarbollide (Cp = eta(5)-C5H5-) with Na+C10H8- in 1,2-dimethoxy-ethane (DME) at room temperature produced an air-sensitive transient anion with a tentatively identified nido-[tBuNH-CpFeC3B8H10](2-) constitution. In-situ reaction of this low-stability ion with [CpFe(CO)(2)I] or [CpFe(CO)(2)](2) generated three violet di-ferratricarbaboranes identified as paramagnetic subcloso complexes [4,5-Cp2--4,5,1,6,7-Fe2C3B8H11] (2; yield 2%), [4,5-CP2--4,5,1,7,12-Fe2C3B8H11] (3; yield 2%), and [7-tBuNH-4,5-Cp2-- 4,5,1,7,12-Fe2C3B8H10] (4; yield 14%). These first representatives of the 13-vertex dimetallatricarbaborane family were characterized by EPR and IR spectroscopy, and mass spectrometry, and their structures were determined by X-ray diffraction analysis.
- Treatment of the [2-Cp-9tBuNH-closo-2,1,7,9-FeC3B8H10] (1) ferratricarbollide (Cp = eta(5)-C5H5-) with Na+C10H8- in 1,2-dimethoxy-ethane (DME) at room temperature produced an air-sensitive transient anion with a tentatively identified nido-[tBuNH-CpFeC3B8H10](2-) constitution. In-situ reaction of this low-stability ion with [CpFe(CO)(2)I] or [CpFe(CO)(2)](2) generated three violet di-ferratricarbaboranes identified as paramagnetic subcloso complexes [4,5-Cp2--4,5,1,6,7-Fe2C3B8H11] (2; yield 2%), [4,5-CP2--4,5,1,7,12-Fe2C3B8H11] (3; yield 2%), and [7-tBuNH-4,5-Cp2-- 4,5,1,7,12-Fe2C3B8H10] (4; yield 14%). These first representatives of the 13-vertex dimetallatricarbaborane family were characterized by EPR and IR spectroscopy, and mass spectrometry, and their structures were determined by X-ray diffraction analysis. (en)
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Title
| - Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series.
- Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. (en)
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skos:prefLabel
| - Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series.
- Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. (en)
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skos:notation
| - RIV/61388980:_____/03:50033041!RIV/2004/MSM/A50004/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/00/1042), P(GA203/01/0944), P(LN00A028), Z(AV0Z4032918)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/03:50033041
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - boranes; carboranes; cluster compounds (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Chemistry A European Journal
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Grüner, Bohumír
- Stopka, Pavel
- Štíbr, Bohumil
- Teixidor, F.
- Kivekäs, R.
- Sillanpää, R.
- Vinas, C.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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