About: Photodissociation of Molecules in Hydrogen Bonded Clusters Probing the Excited State

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	We review our recent results on the photodissociation of hydrogen bonded clusters. They are generated in supersonic expansion and subsequently photolyzed. Hydrogen atoms leaving the clusters are detected and the kinetic energy distributions (KEDs) of these outgoing fragments are determined. In the KED spectra, we distinguish three regimes with an increasing kinetic energy: those products which are slowed down by the cluster cage, those which leave it unperturbed and those which gain energy in processes following primary photodissociation. We have analyzed the shapes of the kinetic energy spectra and identified important reaction channels. Our experiments are accompanied and interpreted with theoretical calculations which are based on state-of the-art ab initio methods, We review our recent results on the photodissociation of hydrogen bonded clusters. They are generated in supersonic expansion and subsequently photolyzed. Hydrogen atoms leaving the clusters are detected and the kinetic energy distributions (KEDs) of these outgoing fragments are determined. In the KED spectra, we distinguish three regimes with an increasing kinetic energy: those products which are slowed down by the cluster cage, those which leave it unperturbed and those which gain energy in processes following primary photodissociation. We have analyzed the shapes of the kinetic energy spectra and identified important reaction channels. Our experiments are accompanied and interpreted with theoretical calculations which are based on state-of the-art ab initio methods, (en)
Title	Photodissociation of Molecules in Hydrogen Bonded Clusters Probing the Excited State Photodissociation of Molecules in Hydrogen Bonded Clusters Probing the Excited State (en)
skos:prefLabel	Photodissociation of Molecules in Hydrogen Bonded Clusters Probing the Excited State Photodissociation of Molecules in Hydrogen Bonded Clusters Probing the Excited State (en)
skos:notation	RIV/61388955:_____/11:00349494!RIV12-GA0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/09/0422), P(KAN400400651), Z(AV0Z40400503)
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Fárník, Michal
http://linked.open.../riv/druhVysledku	C - Kapitola v knize
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	220243
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/11:00349494
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	photodissociation; hydrogen bonded clusters; pure and doped water clusters (en)
http://linked.open.../riv/klicoveSlovo	hydrogen bonded clusters photodissociation pure and doped water clusters
http://linked.open...ontrolniKodProRIV	[6F0E1D34342C]
http://linked.open...i/riv/mistoVydani	Chichester
http://linked.open...i/riv/nazevZdroje	Hydrogen Bonding and Transfer in the Excited State
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...v/pocetStranKnihy	907 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Study of photochemical processes in free nanoparticles of atmospheric and biophysical relevance Experimentální a teoretické studium volných nanočástic: %22létající nanoreaktory%22 pro výzkum procesů na molekulární úrovni
http://linked.open...UplatneniVysledku	2011
http://linked.open...iv/tvurceVysledku	Fárník, Michal Slavíček, P. Buck, U.
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
number of pages	27 (xsd:int)
http://purl.org/ne...btex#hasPublisher	John Wiley & Sons Ltd
https://schema.org/isbn	978-0-470-66677-7

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