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rdf:type
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Description
| - The paramagnetic compound [Ru(NO)(Q)(terpy)](PF6)2 (Q = 4,6-Di-tert.-butyl-N-phenyl-o-iminobenzoquinone) was prepared via the intermediates [RuCl(Q)(terpy)](ClO4) and [Ru(NO2)(Q)(terpy)](ClO4). The more stable positional isomer with NO trans to the O donor atom of Q was isolated and characterized. In conjunction with the X-ray crystal structure, IR and EPR studies suggest [RuII(NO+)(Q-)(terpy)]2+ as the most valid oxidation state formulation. DFT calculations confirm oxidation state assignment.
- The paramagnetic compound [Ru(NO)(Q)(terpy)](PF6)2 (Q = 4,6-Di-tert.-butyl-N-phenyl-o-iminobenzoquinone) was prepared via the intermediates [RuCl(Q)(terpy)](ClO4) and [Ru(NO2)(Q)(terpy)](ClO4). The more stable positional isomer with NO trans to the O donor atom of Q was isolated and characterized. In conjunction with the X-ray crystal structure, IR and EPR studies suggest [RuII(NO+)(Q-)(terpy)]2+ as the most valid oxidation state formulation. DFT calculations confirm oxidation state assignment. (en)
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Title
| - An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands
- An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands (en)
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skos:prefLabel
| - An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands
- An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands (en)
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skos:notation
| - RIV/61388955:_____/09:00327321!RIV10-MSM-61388955
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(KAN100400702), P(OC 139), Z(AV0Z40400503)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/09:00327321
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - nitrosyl complexes; non-innocent ligands; quinones; radical ligands; ruthenium (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Angewandte Chemie. International Edition in English
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Fiedler, Jan
- Kaim, W.
- Lahiri, G. K.
- Sarkar, B.
- Záliš, Stanislav
- Strobel, S.
- Das, A. K.
- Duboc, C.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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