About: N2O Decomposition over Fe-Ferrierite: Primary and Secondary Reactions with Reducing Agents

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The decomposition of N2O either alone or with several reducing agents (CH4, CO, NO and D-2) was followed by temperature-programmed desorption of surface species formed during the reactions. TPD products formed in these %22primary%22 reactions were compared with the TPD products after %22secondary%22 reactions of the same set of reducing agents with the surface species formed during the primary reactions. Changes in TPD products after reactions measured under various conditions were analyzed in detail. These experiments provided a background for studies of the nature and reactivity of surface species formed during N2O reactions over Fe-ferrierite. The relevance of these experimental results to the mechanism of the N2O elimination is discussed. The decomposition of N2O either alone or with several reducing agents (CH4, CO, NO and D-2) was followed by temperature-programmed desorption of surface species formed during the reactions. TPD products formed in these %22primary%22 reactions were compared with the TPD products after %22secondary%22 reactions of the same set of reducing agents with the surface species formed during the primary reactions. Changes in TPD products after reactions measured under various conditions were analyzed in detail. These experiments provided a background for studies of the nature and reactivity of surface species formed during N2O reactions over Fe-ferrierite. The relevance of these experimental results to the mechanism of the N2O elimination is discussed. (en) Rozklad N2O buď samotného nebo spolu s některými redukčními činidly (CH4, CO, NO a D2) byl studován pomocí teplotně programované desorpce (TPD) povrchových specií vytvořených během těchto reakcí. TPD produkty vytvořené během těchto %22primárních%22 reakcí byly porovnávány s TPD produkty %22sekundárních%22 reakcí těchže redukčních činidel s povrchovými speciemi vutvořenými během primárních reakcí. Podrobně byly analyzovány změny v obou druzích TPD produktů po reakcích měřených za různých podmínek. Tyto experimenty poskytují základy pro studie povahy a reaktivity povrchových sloučenin tvořených během reakcí N2O na Fe-ferrieritu. Diskutují se vztahy získaných experimentálních dat s mechanismem eliminace N2O. (cs)
Title	N2O Decomposition over Fe-Ferrierite: Primary and Secondary Reactions with Reducing Agents N2O Decomposition over Fe-Ferrierite: Primary and Secondary Reactions with Reducing Agents (en) Rozklad N2O na Fe-ferrieritu: primární a sekundární reakce (cs)
skos:prefLabel	N2O Decomposition over Fe-Ferrierite: Primary and Secondary Reactions with Reducing Agents N2O Decomposition over Fe-Ferrierite: Primary and Secondary Reactions with Reducing Agents (en) Rozklad N2O na Fe-ferrieritu: primární a sekundární reakce (cs)
skos:notation	RIV/61388955:_____/09:00322810!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(1ET400400413), P(1QS400400560), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Sobalík, Zdeněk Nováková, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	330349
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/09:00322810
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	N2O decomposition; reactivity of surface species; Fe-ferrierite (en)
http://linked.open.../riv/klicoveSlovo	reactivity of surface species Fe-ferrierite N2O decomposition
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[66143B031A1E]
http://linked.open...i/riv/nazevZdroje	Catalysis Letters
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Development of a program environment for mathematic simulations and predictions in catalysis and electrocatalysis Joint laboratory of ÚFCH JH and VÚANCH for development of catalytic processes
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	127
http://linked.open...iv/tvurceVysledku	Nováková, Jana Sobalík, Zdeněk
http://linked.open...ain/vavai/riv/wos	000261786400015
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	1011-372X
number of pages	6 (xsd:int)

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