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rdf:type
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Description
| - From extraction experiments and ?-activity measurements, the extraction constant corresponding to the equilibrium Li+(aq) + 1.Na+(nb) ? 1.Li+(nb) + Na+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex(1.Na+) = 0.5 +- 0.1. Further, the stability constant of the 1.Li+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 oC as log ?nb(1.Li+) = 5.6 +- 0.2. By using DFT calculations, the most probable structures of the non-hydrated 1.Li+ and hydrated 1.Li.3H2O complex species were predicted.
- From extraction experiments and ?-activity measurements, the extraction constant corresponding to the equilibrium Li+(aq) + 1.Na+(nb) ? 1.Li+(nb) + Na+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex(1.Na+) = 0.5 +- 0.1. Further, the stability constant of the 1.Li+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 oC as log ?nb(1.Li+) = 5.6 +- 0.2. By using DFT calculations, the most probable structures of the non-hydrated 1.Li+ and hydrated 1.Li.3H2O complex species were predicted. (en)
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Title
| - Complexation of the lithium cation with beauvericin: Experimental and DFT study
- Complexation of the lithium cation with beauvericin: Experimental and DFT study (en)
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skos:prefLabel
| - Complexation of the lithium cation with beauvericin: Experimental and DFT study
- Complexation of the lithium cation with beauvericin: Experimental and DFT study (en)
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skos:notation
| - RIV/60461373:22340/12:43893334!RIV13-MSM-22340___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - I, P(GAP205/10/2280), S, Z(AV0Z40500505)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22340/12:43893334
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Structure; Beauvericin; Lithium; Complexation; DFT; Extraction (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Molecular Structure
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Makrlík, Emanuel
- Toman, Petr
- Vaňura, Petr
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.molstruc.2012.05.009
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http://localhost/t...ganizacniJednotka
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