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  • The millimeter-wave rotational spectrum of TiO(2) in its ground vibrational state has been recorded in the frequency range from 248 to 345 GHz using the Cologne Supersonic Jet Spectrometer for Terahertz Applications (SuJeSTA). Forty-two b-type rotational transitions of the main isotopologue (48)TiO(2) and five transitions of (46)TiO(2) in natural abundance have been measured up to J = 22 and K(a) = 8 which corresponds to excitation temperatures of 170 K. TiO(2) was formed by laser ablation and adiabatically cooled in a supersonic jet of helium to rotational temperatures of 20 K. The new transitions have been analyzed together with previously reported data obtained from Fourier-transform microwave spectroscopy in the frequency range from 7 to 42 GHz. The improved and extended set of spectroscopic parameters provides accurate transition frequencies for future astronomical searches in the millimeter-wave region.
  • The millimeter-wave rotational spectrum of TiO(2) in its ground vibrational state has been recorded in the frequency range from 248 to 345 GHz using the Cologne Supersonic Jet Spectrometer for Terahertz Applications (SuJeSTA). Forty-two b-type rotational transitions of the main isotopologue (48)TiO(2) and five transitions of (46)TiO(2) in natural abundance have been measured up to J = 22 and K(a) = 8 which corresponds to excitation temperatures of 170 K. TiO(2) was formed by laser ablation and adiabatically cooled in a supersonic jet of helium to rotational temperatures of 20 K. The new transitions have been analyzed together with previously reported data obtained from Fourier-transform microwave spectroscopy in the frequency range from 7 to 42 GHz. The improved and extended set of spectroscopic parameters provides accurate transition frequencies for future astronomical searches in the millimeter-wave region. (en)
Title
  • Millimeter-wave spectroscopy of titanium dioxide, TiO(2)
  • Millimeter-wave spectroscopy of titanium dioxide, TiO(2) (en)
skos:prefLabel
  • Millimeter-wave spectroscopy of titanium dioxide, TiO(2)
  • Millimeter-wave spectroscopy of titanium dioxide, TiO(2) (en)
skos:notation
  • RIV/60461373:22340/11:43891825!RIV12-MSM-22340___
http://linked.open...avai/riv/aktivita
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  • V
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  • 1
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  • 212549
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  • RIV/60461373:22340/11:43891825
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  • Millimeter-wave spectroscopy; Interstellar molecule; Transition metal; Titanium dioxide (en)
http://linked.open.../riv/klicoveSlovo
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  • US - Spojené státy americké
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  • [E32E9AAD60E7]
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  • Journal of Molecular Spectroscopy
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  • 268
http://linked.open...iv/tvurceVysledku
  • Kania, Patrik
  • Brünken, Sandra
  • Giesen, Thomas F.
  • Hermanns, Marius
  • Müller, Holger S. P.
http://linked.open...ain/vavai/riv/wos
  • 000294833100024
issn
  • 0022-2852
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jms.2011.04.013
http://localhost/t...ganizacniJednotka
  • 22340
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