About: Solvent extraction of microamounts of cesium into nitrobenzene by using potassium and rubidium dicarbollylcobaltates in the presence of benzo 15 crown-5

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About: Solvent extraction of microamounts of cesium into nitrobenzene by using potassium and rubidium dicarbollylcobaltates in the presence of benzo 15 crown-5 Goto Sponge Distinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Byla sledována extrakce mikrokoncentrací cesia roztokem sodné a draselné sole dikarbollylkobaltitanu (H+B-) v nitrobenzenu za přítomnosti benzo 15 crown 5 (L). Bylo zjištěno, že do organické fáze přecházejí komplexu HL+, ML+a ML2+ (M+ = K+, Rb+, Cs+) a spočteny hodnoty jejich rovnovážných extrakčních konstant a konstant stability v nitrobenzenu, nasyceném vodou. (cs) Extraction of microamounts of cesium by nitrobenzene solutions of potassium dicarbollylcobaltate (K+B-) and rubidium dicarbollylcobaltate (Rb+B-) in the presence of benzo-15-crown-5 (B15C5, L) has been investigated. The equilibrium data have been explained assuming that the complexes ML+ and ML2+ (M+ = K+, Rb+, Cs+) are present in the organic phase. The stability constants of the species ML+ and ML2+ (M+ = K+, Rb+) in nitrobenzene saturated with water have been determined. Extraction of microamounts of cesium by nitrobenzene solutions of potassium dicarbollylcobaltate (K+B-) and rubidium dicarbollylcobaltate (Rb+B-) in the presence of benzo-15-crown-5 (B15C5, L) has been investigated. The equilibrium data have been explained assuming that the complexes ML+ and ML2+ (M+ = K+, Rb+, Cs+) are present in the organic phase. The stability constants of the species ML+ and ML2+ (M+ = K+, Rb+) in nitrobenzene saturated with water have been determined. (en)
Title	Solvent extraction of microamounts of cesium into nitrobenzene by using potassium and rubidium dicarbollylcobaltates in the presence of benzo 15 crown-5 Solvent extraction of microamounts of cesium into nitrobenzene by using potassium and rubidium dicarbollylcobaltates in the presence of benzo 15 crown-5 (en) Extrakce mikromnožství cesia roztokem sodné a draselné sole dikarbollylkobaltitanu v nitrobenzenu za přítomnosti benzo-15-crown-5 (cs)
skos:prefLabel	Solvent extraction of microamounts of cesium into nitrobenzene by using potassium and rubidium dicarbollylcobaltates in the presence of benzo 15 crown-5 Solvent extraction of microamounts of cesium into nitrobenzene by using potassium and rubidium dicarbollylcobaltates in the presence of benzo 15 crown-5 (en) Extrakce mikromnožství cesia roztokem sodné a draselné sole dikarbollylkobaltitanu v nitrobenzenu za přítomnosti benzo-15-crown-5 (cs)
skos:notation	RIV/60461373:22340/08:00020719!RIV09-MSM-22340___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM4977751303), Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Vaňura, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	395849
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/08:00020719
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	water-nitrobenzene; cesium; rubidium; potassium; complexes; benzo-15-crown-5 (en)
http://linked.open.../riv/klicoveSlovo	cesium rubidium complexes potassium benzo-15-crown-5 water-nitrobenzene
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[34EB2C2107CC]
http://linked.open...i/riv/nazevZdroje	Journal of Radioanalytical and Nuclear Chemistry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	275
http://linked.open...iv/tvurceVysledku	Makrlík, E. Vaňura, Petr Selucký, P.
http://linked.open...ain/vavai/riv/wos	000251867200030
http://linked.open...n/vavai/riv/zamer	Predikce poruch heterogenních materiálů, komponent mechanických a biomechanických systémů. Physico-chemical methods of analysis and characterization of chemical systems and biosystems
issn	0236-5731
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	22340

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