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  • DART (direct analysis in real time) is a novel technique with great potential for rapid screening analysis. The DART ionization method coupled with high-resolution time-of-flight mass spectrometry (TOF-MS) has been used for characterization of mustard seeds and table mustard. The possibility to use DART to analyse glucosinolates was confirmed on determination of sinalbin (4-hydroxybenzyl glucosinolate). The DART-TOF-MS method was optimized and validated. A set of samples of mustard seeds and mustard products was analyzed. HPLC and DART-TOF-MS were used to determine glucosinolates in mustard seeds and compared. The correlation equation between these methods was DART = 0.797HPLC+6.987, R2=0.972. The DART technique seems to be a suitable method for evaluation of the quality of mustard seeds and mustard products.
  • DART (direct analysis in real time) is a novel technique with great potential for rapid screening analysis. The DART ionization method coupled with high-resolution time-of-flight mass spectrometry (TOF-MS) has been used for characterization of mustard seeds and table mustard. The possibility to use DART to analyse glucosinolates was confirmed on determination of sinalbin (4-hydroxybenzyl glucosinolate). The DART-TOF-MS method was optimized and validated. A set of samples of mustard seeds and mustard products was analyzed. HPLC and DART-TOF-MS were used to determine glucosinolates in mustard seeds and compared. The correlation equation between these methods was DART = 0.797HPLC+6.987, R2=0.972. The DART technique seems to be a suitable method for evaluation of the quality of mustard seeds and mustard products. (en)
Title
  • Characterization of mustard seeds and paste by DART ionization with time-of-flight mass spectrometry
  • Characterization of mustard seeds and paste by DART ionization with time-of-flight mass spectrometry (en)
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  • Characterization of mustard seeds and paste by DART ionization with time-of-flight mass spectrometry
  • Characterization of mustard seeds and paste by DART ionization with time-of-flight mass spectrometry (en)
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  • RIV/60461373:22330/14:43897146!RIV15-MZE-22330___
http://linked.open...avai/riv/aktivita
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  • P(QI91B283), S
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  • 9
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  • 6955
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  • RIV/60461373:22330/14:43897146
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  • mass spectrometry; fingerprints; sinalbin; mustard seed; mustard; HPLC; DART (en)
http://linked.open.../riv/klicoveSlovo
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  • US - Spojené státy americké
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  • [F028A7A3F01B]
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  • Journal of Mass Spectrometry
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  • 49
http://linked.open...iv/tvurceVysledku
  • Ševčík, Rudolf
  • Rajchl, Aleš
  • Čížková, Helena
  • Kovařík, František
  • Prchalová, Jana
issn
  • 1076-5174
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/jms.3419
http://localhost/t...ganizacniJednotka
  • 22330
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