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rdf:type
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Description
| - Only four types of dimeric precursors [RuCl2(éta6-arene)]2 for the synthesis of Noyori's half sandwich diamine catalysts [RuCl(TsDPEN)(éta6-arene)] are commercially available, yet so far no study has tried to systematically evaluate how these systems perform during the asymmetric transfer hydrogenation of various 3,4-dihydroisoquinolines (i.e., the typical substrates for Noyori asymmetric transfer hydrogenation benchmarking). Experiments combined with molecular modeling allowed us to assess their properties and formulate a hypothesis clarifying the difference in enantioselectivity of these systems.
- Only four types of dimeric precursors [RuCl2(éta6-arene)]2 for the synthesis of Noyori's half sandwich diamine catalysts [RuCl(TsDPEN)(éta6-arene)] are commercially available, yet so far no study has tried to systematically evaluate how these systems perform during the asymmetric transfer hydrogenation of various 3,4-dihydroisoquinolines (i.e., the typical substrates for Noyori asymmetric transfer hydrogenation benchmarking). Experiments combined with molecular modeling allowed us to assess their properties and formulate a hypothesis clarifying the difference in enantioselectivity of these systems. (en)
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Title
| - The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts
- The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts (en)
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skos:prefLabel
| - The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts
- The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts (en)
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skos:notation
| - RIV/60461373:22310/14:43897968!RIV15-GA0-22310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22310/14:43897968
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - arene; imines; ruthenium (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Kačer, Petr
- Kuzma, Marek
- Václavík, Jiří
- Vilhanová, Beáta
- Pecháček, Jan
- Zápal, Jakub
- Šot, Petr
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.tetasy.2014.08.011
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http://localhost/t...ganizacniJednotka
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