About: Synergistic Extraction of Calcium and Strontium Into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate and 1,2-Bis(Diphenylphosphino)Ethane Dioxide

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About: Synergistic Extraction of Calcium and Strontium Into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate and 1,2-Bis(Diphenylphosphino)Ethane Dioxide Goto Sponge Distinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of 1,2-bis(diphenylphosphino) ethane dioxide (DPPEtDO, L) has been investigated. The equilibrium data have been explained assuming that the species HL+, HL2+ , ML22+ and ML32+ (M2+ = Ca2+, Sr2+) are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the complexes CaL22+ and CaL32+, where L is DPPEtDO, are somewhat higher than those of the corresponding complex species SrL22+ and SrL32+ with the same ligand L. Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of 1,2-bis(diphenylphosphino) ethane dioxide (DPPEtDO, L) has been investigated. The equilibrium data have been explained assuming that the species HL+, HL2+ , ML22+ and ML32+ (M2+ = Ca2+, Sr2+) are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the complexes CaL22+ and CaL32+, where L is DPPEtDO, are somewhat higher than those of the corresponding complex species SrL22+ and SrL32+ with the same ligand L. (en)
Title	Synergistic Extraction of Calcium and Strontium Into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate and 1,2-Bis(Diphenylphosphino)Ethane Dioxide Synergistic Extraction of Calcium and Strontium Into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate and 1,2-Bis(Diphenylphosphino)Ethane Dioxide (en)
skos:prefLabel	Synergistic Extraction of Calcium and Strontium Into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate and 1,2-Bis(Diphenylphosphino)Ethane Dioxide Synergistic Extraction of Calcium and Strontium Into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate and 1,2-Bis(Diphenylphosphino)Ethane Dioxide (en)
skos:notation	RIV/46356088:_____/12:#0001250!RIV13-MPO-46356088
http://linked.open...avai/riv/aktivita	N S
http://linked.open...avai/riv/aktivity	N, S
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Selucký, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	ÚJV Řež, a. s.
http://linked.open...dnocenehoVysledku	172866
http://linked.open...ai/riv/idVysledku	RIV/46356088:_____/12:#0001250
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Calcium; strontium; hydrogen dicarbollylcobaltate; extraction and stability constants; water-nitrobenzene system (en)
http://linked.open.../riv/klicoveSlovo	strontium Calcium extraction and stability constants hydrogen dicarbollylcobaltate water-nitrobenzene system
http://linked.open...odStatuVydavatele	SI - Slovinská republika
http://linked.open...ontrolniKodProRIV	[0A733441C08E]
http://linked.open...i/riv/nazevZdroje	Acta Chimica Slovenica
http://linked.open...in/vavai/riv/obor	CH
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	59
http://linked.open...iv/tvurceVysledku	Makrlík, Emanuel Selucký, Pavel
http://linked.open...ain/vavai/riv/wos	000313199100032
issn	1318-0207
number of pages	6 (xsd:int)

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