About: Synthesis of Large Dendrimers with the Dimensions of Small Viruses

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The dendrimer chemistry reported offers a route to synthetic target molecules with spherical shape, well-defined surface chemistries and dimensions that match the size of virus particles. The largest target, a generation 13 dendrimer comprising triazines linked by diamines, is stable across ranges of concentration, pH, temperature, solvent polarity and in the presence of additives. This dendrimer theoretically, presents 16384 surface groups and has a molecular weight exceeding 8.4 million Daltons. Transmission electron and atomic force microscopies, dynamic light scattering and computation reveal a diameter of approximately 30 nm. The target is synthesized through an iterative divergent approach using a monochlorotriazine macromonomer providing two generations of growth per synthetic cycle. Fidelity in synthesis is supported by evidence from NMR spectroscopy, mass spectrometry and high pressure liquid chromatography. The dendrimer chemistry reported offers a route to synthetic target molecules with spherical shape, well-defined surface chemistries and dimensions that match the size of virus particles. The largest target, a generation 13 dendrimer comprising triazines linked by diamines, is stable across ranges of concentration, pH, temperature, solvent polarity and in the presence of additives. This dendrimer theoretically, presents 16384 surface groups and has a molecular weight exceeding 8.4 million Daltons. Transmission electron and atomic force microscopies, dynamic light scattering and computation reveal a diameter of approximately 30 nm. The target is synthesized through an iterative divergent approach using a monochlorotriazine macromonomer providing two generations of growth per synthetic cycle. Fidelity in synthesis is supported by evidence from NMR spectroscopy, mass spectrometry and high pressure liquid chromatography. (en)
Title	Synthesis of Large Dendrimers with the Dimensions of Small Viruses Synthesis of Large Dendrimers with the Dimensions of Small Viruses (en)
skos:prefLabel	Synthesis of Large Dendrimers with the Dimensions of Small Viruses Synthesis of Large Dendrimers with the Dimensions of Small Viruses (en)
skos:notation	RIV/44555601:13440/13:43884961!RIV14-GA0-13440___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA13-06609S), P(OC10053)
http://linked.open...iv/cisloPeriodika	12
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Malý, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Jana Evangelisty Purkyně v Ústí nad Labem / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	109534
http://linked.open...ai/riv/idVysledku	RIV/44555601:13440/13:43884961
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	polymers; micelles; nanostructures; macromolecules; janus dendrimers; triazine dendrimers (en)
http://linked.open.../riv/klicoveSlovo	polymers janus dendrimers triazine dendrimers micelles macromolecules nanostructures
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[76C4D5CCEF19]
http://linked.open...i/riv/nazevZdroje	Journal Of The American Chemical Society
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Příprava nano a mikrostruktur na substrátu interakcí s laserovým svazkem DENDRIMERS IN BIOMEDICAL APPLICATIONS
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	135
http://linked.open...iv/tvurceVysledku	Malý, Jan Pavan, Giovanni M. Annunziata, Onofrio Da Costa, V.C.P. Kostiainen, Mauri A. Lim, Jongdoo Simanek, Eric C.
http://linked.open...ain/vavai/riv/wos	000317032000022
issn	0002-7863
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/ja400432e
http://localhost/t...ganizacniJednotka	13440

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