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rdf:type
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Description
| - Two types of vanadocene complexes with carboxylic acids have been synthesized from the aqueous solution, Cp2V(OOCR)(2) (R = H, CCl3 and CF3) and Cp2V(OOC-A-COO) (A = - and CH2), and characterized by EPR, IR, and Raman spectroscopy and X-ray diffraction analysis. Monocarboxylic and dicarboxylic acids form monodentate and chelate complexes, respectively. Both bonding types were evidenced by X-ray diffraction analysis. Structures and EPR HFC tensors were also calculated at the DFT level. Correlation between the complex structure and HFC tensor was established. HFC tensors are characteristic for the type of bond of carboxylic acid on vanadocene fragment. It is shown that the structure of complexes can be determined by the combination of theoretical method with experimental EPR spectra
- Two types of vanadocene complexes with carboxylic acids have been synthesized from the aqueous solution, Cp2V(OOCR)(2) (R = H, CCl3 and CF3) and Cp2V(OOC-A-COO) (A = - and CH2), and characterized by EPR, IR, and Raman spectroscopy and X-ray diffraction analysis. Monocarboxylic and dicarboxylic acids form monodentate and chelate complexes, respectively. Both bonding types were evidenced by X-ray diffraction analysis. Structures and EPR HFC tensors were also calculated at the DFT level. Correlation between the complex structure and HFC tensor was established. HFC tensors are characteristic for the type of bond of carboxylic acid on vanadocene fragment. It is shown that the structure of complexes can be determined by the combination of theoretical method with experimental EPR spectra (en)
- Syntéza, charakterizace a strukturní výzkum komplexů vanadocen(IV) kyseliny karboxylové připravených z vanadocen dichloridu (cs)
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Title
| - Syntéza, charakterizace a strukturní výzkum komplexů vanadocen(IV) kyseliny karboxylové připravených z vanadocen dichloridu (cs)
- Synthesis, characterization and structural investigation of the first vanadocene(IV) carboxylic acid complexes prepared from the vanadocene dichloride
- Synthesis, characterization and structural investigation of the first vanadocene(IV) carboxylic acid complexes prepared from the vanadocene dichloride (en)
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skos:prefLabel
| - Syntéza, charakterizace a strukturní výzkum komplexů vanadocen(IV) kyseliny karboxylové připravených z vanadocen dichloridu (cs)
- Synthesis, characterization and structural investigation of the first vanadocene(IV) carboxylic acid complexes prepared from the vanadocene dichloride
- Synthesis, characterization and structural investigation of the first vanadocene(IV) carboxylic acid complexes prepared from the vanadocene dichloride (en)
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skos:notation
| - RIV/00216275:25310/04:00001399!RIV08-MSM-25310___
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - Z(MSM 113100001), Z(MSM 253100001)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/04:00001399
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - vanadocene dichloride; antitumor agent; X-ray; EPR; DFT (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Císařová, Ivana
- Nachtigall, Petr
- Vinklárek, Jaromír
- Honzíček, Jan
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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