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  • The effect of the deaeration on the adsorption of three cationic surfactants cetyldimethylbenzylammonium chloride (CDBACl), cetyltrimethylammonium bromide (CTAB) and octadecyltrimethylammonium bromide (OTAB) at the mercury electrolyte solution interface is studied. The deaeration is studied using either nitrogen or helium and the effect of deaeration process and time is also studied. In all cases an effect of the deaeration time is found which is mainly observed at potentials where a condensed film is formed. Capacity time curves at the potentials where the film is formed show a nucleation and growth mechanism with induction time that depends on the deaeration time. The deaeration slows down the kinetics of the film formation but does not change the equilibrium capacitance value of the film. The decrease of the dissolved gas from the water that perturbs its structure is perhaps the main reason for the behaviour observed during the adsorption of these surfactants.
  • The effect of the deaeration on the adsorption of three cationic surfactants cetyldimethylbenzylammonium chloride (CDBACl), cetyltrimethylammonium bromide (CTAB) and octadecyltrimethylammonium bromide (OTAB) at the mercury electrolyte solution interface is studied. The deaeration is studied using either nitrogen or helium and the effect of deaeration process and time is also studied. In all cases an effect of the deaeration time is found which is mainly observed at potentials where a condensed film is formed. Capacity time curves at the potentials where the film is formed show a nucleation and growth mechanism with induction time that depends on the deaeration time. The deaeration slows down the kinetics of the film formation but does not change the equilibrium capacitance value of the film. The decrease of the dissolved gas from the water that perturbs its structure is perhaps the main reason for the behaviour observed during the adsorption of these surfactants. (en)
Title
  • Effect of the deaeration on the adsorption of some cationic surfactants
  • Effect of the deaeration on the adsorption of some cationic surfactants (en)
skos:prefLabel
  • Effect of the deaeration on the adsorption of some cationic surfactants
  • Effect of the deaeration on the adsorption of some cationic surfactants (en)
skos:notation
  • RIV/00216224:14310/06:00026333!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 143100011), Z(MSM0021622412)
http://linked.open...iv/cisloPeriodika
  • 296
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 473228
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/06:00026333
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Cetyldimethylbenzylammonium chloride; Cetyltrimethylammonium bromide; Octadecyltrimethylammonium bromide; Nitrogen; Helium; Deaeration (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [3AB5506D0117]
http://linked.open...i/riv/nazevZdroje
  • Journal of Colloid and Interface Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 296
http://linked.open...iv/tvurceVysledku
  • Kebrlová, Natálie
  • Avranas, Antonis
  • Koimtzoglou, Pantelis
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9797
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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