About: Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic

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About: Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds Goto Sponge Distinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reactions in the CuSO4–phen–KVO3–H2O–(KOH) systems under non-hydrothermal conditions yielded seven new compounds: [Cu2(H2O)2(OH)2(phen)2][Cu2(OH)2(phen)2(V4O12)].6H2O (3), [Cu2(phen)4(V4O12)].4H2O (4), [Cu2(phen)4(V4O12)].6H2O (5), [Cu2(phen)4(VO3)4].10H2O (6), [Cu(phen)3]2V4O12.phen.22H2O (7), [Cu(phen)(VO3)2] (9) and [Cu2(phen)4(V4O12)].4H2O (12). The prepared compounds were characterized by elemental analyses and IR spectra. The characteristic bands in the IR spectra corresponding to the V–O stretching modes enabled the different oxovanadate groups present in the structures to be unequivocally distinguished. Compounds 3, 4, 5, 6, 7 and 12 were characterized by X-ray single crystal diffraction. The structure of compound 3 consists of isolated dinuclear [(phen)(H2O)Cu(mu-OH)2Cu(phen)(H2O)]2+ ions and [(phen)Cu(OH)2Cu(phen)]2+ moieties attached to Click to view the MathML source rings. Reactions in the CuSO4–phen–KVO3–H2O–(KOH) systems under non-hydrothermal conditions yielded seven new compounds: [Cu2(H2O)2(OH)2(phen)2][Cu2(OH)2(phen)2(V4O12)].6H2O (3), [Cu2(phen)4(V4O12)].4H2O (4), [Cu2(phen)4(V4O12)].6H2O (5), [Cu2(phen)4(VO3)4].10H2O (6), [Cu(phen)3]2V4O12.phen.22H2O (7), [Cu(phen)(VO3)2] (9) and [Cu2(phen)4(V4O12)].4H2O (12). The prepared compounds were characterized by elemental analyses and IR spectra. The characteristic bands in the IR spectra corresponding to the V–O stretching modes enabled the different oxovanadate groups present in the structures to be unequivocally distinguished. Compounds 3, 4, 5, 6, 7 and 12 were characterized by X-ray single crystal diffraction. The structure of compound 3 consists of isolated dinuclear [(phen)(H2O)Cu(mu-OH)2Cu(phen)(H2O)]2+ ions and [(phen)Cu(OH)2Cu(phen)]2+ moieties attached to Click to view the MathML source rings. (en)
Title	Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds (en)
skos:prefLabel	Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds (en)
skos:notation	RIV/00216224:14310/06:00017824!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/99/M037), Z(MSM0021622415)
http://linked.open...iv/cisloPeriodika	13
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Marek, Jaromír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	501948
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/06:00017824
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Crystal structures; Copper–phenanthroline oxovanadates; Hybrid inorganic–organic compounds; IR spectra (en)
http://linked.open.../riv/klicoveSlovo	IR spectra Crystal structures Copper–phenanthroline oxovanadates Hybrid inorganic–organic compounds
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[AE02AF03A12D]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of molecular and crystal structures
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	25
http://linked.open...iv/tvurceVysledku	Marek, Jaromír Gyepes, R. Schwendt, P. Mička, Z. Joniaková, D. Rakovský, E. Žúrková, L.
http://linked.open...n/vavai/riv/zamer	Molecular basis of cell and tissue regulations
issn	0277-5387
number of pages	12 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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