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  • A dealkylsilylation reaction of alumazene [2,6-( i-Pr)2C6H3NAlMe]3 (1) with trimethylsilyl methylsulfonate in a 1:2 molar ratio in toluene afforded a supramolecular cyclic hexamer {Me[2,6-( i-Pr)2C6H3NAl]3- (O3SMe)2}6 (2) composed of six intact alumazene rings and possessing two types of bridging sulfonate groups. Changing the reagent molar ratio to 1:3 caused the third sulfonate to partially substitute the last alumazene methyl group in an eta2 fashion and introduced a disorder in the crystal lattice.
  • A dealkylsilylation reaction of alumazene [2,6-( i-Pr)2C6H3NAlMe]3 (1) with trimethylsilyl methylsulfonate in a 1:2 molar ratio in toluene afforded a supramolecular cyclic hexamer {Me[2,6-( i-Pr)2C6H3NAl]3- (O3SMe)2}6 (2) composed of six intact alumazene rings and possessing two types of bridging sulfonate groups. Changing the reagent molar ratio to 1:3 caused the third sulfonate to partially substitute the last alumazene methyl group in an eta2 fashion and introduced a disorder in the crystal lattice. (en)
Title
  • A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate
  • A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate (en)
skos:prefLabel
  • A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate
  • A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate (en)
skos:notation
  • RIV/00216224:14310/06:00015819!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/04/0296), Z(MSM0021622410)
http://linked.open...iv/cisloPeriodika
  • 17
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 463873
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/06:00015819
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • dealkylsilylation; alumazene; methylsulfonate (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [792873827A59]
http://linked.open...i/riv/nazevZdroje
  • INORGANIC CHEMISTRY
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 45
http://linked.open...iv/tvurceVysledku
  • Pinkas, Jiří
  • Löbl, Jiří
  • Roesky, Herbert W.
  • Görls, Helmar
  • Plass, Winfried
http://linked.open...n/vavai/riv/zamer
issn
  • 0020-1669
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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