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  • The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity.Two selected functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linear. The peak potentials differ in these elimination functions. The difference in EVLS peak potentials gives the possibility to evaluate .EVLS contributes to the resolution of cathodic signals of purine and pyrimidine bases at very ne
  • The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity.Two selected functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linear. The peak potentials differ in these elimination functions. The difference in EVLS peak potentials gives the possibility to evaluate .EVLS contributes to the resolution of cathodic signals of purine and pyrimidine bases at very ne (en)
Title
  • Elimination Voltammetry of Adenine and Cytosine Mixtures
  • Elimination Voltammetry of Adenine and Cytosine Mixtures (en)
skos:prefLabel
  • Elimination Voltammetry of Adenine and Cytosine Mixtures
  • Elimination Voltammetry of Adenine and Cytosine Mixtures (en)
skos:notation
  • RIV/00216224:14310/01:00005416!RIV/2002/MSM/143102/N
http://linked.open.../vavai/riv/strany
  • 131
http://linked.open...avai/riv/aktivita
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  • P(GV204/97/K084), Z(MSM 143100011)
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  • 54
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  • 679253
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  • RIV/00216224:14310/01:00005416
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  • Elimination voltammetry with linear scan, cytosine, adenine, reduction of bases, hydrogen evolution (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [902D8F8967F3]
http://linked.open...i/riv/nazevZdroje
  • Bioelectrochemistry
http://linked.open...in/vavai/riv/obor
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2001
http://linked.open...iv/tvurceVysledku
  • Friml, Jiří
  • Trnková, Libuše
  • Dračka, Oldřich
http://linked.open...n/vavai/riv/zamer
issn
  • 1567-5394
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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