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Description
  • A new series of 2,8'-disubstituted binaphthyls will be prepared. Preparation of new monodentate ligands that should be less prone to racemization is one of the goals of the project. New bidentate ligands that can be regarded as positional isomers of thei2,2'-disubstituted congeners will be also prepared. Complexes of the new ligands with transition metals will be employed as catalysts for selected asymmetric processes. (en)
  • BŘhem projektu budou pýipraveny nov‚ 2,8'-disubstituovan‚ binaftyly. Jednˇm z cˇl… projektu je pýˇprava nověch monodent tnˇch ligand… se zvěçenou stabilitou v…źi racemizaci. D le budou pýipraveny nov‚ bident tnˇ ligandy, kter‚ je mo§n‚ pova§ovat jako poziźnˇ isomery ji§ osvŘdźeněch 2,2'-disubstituovaněch binaftyl…. Komplexy nověch ligand… s pýechodněmi kovy budou pou§ity jako katalyz tory vybraněch asymetrickěch proces….
Title
  • Novel monodentate and bidentate ligands and their use in asymmetric catalysis (en)
  • Nov‚ monodent tnˇ a bident tnˇ ligandy pro asymetrickou katalězu
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  • GP203/01/D051
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  • Projekt byl pýedźasnŘ ukonźen na § dost ýeçitele. V r mci projektu byly pýipraveny nov‚ týi typy enantiomernŘ źistěch ligand…, kter‚ se uk zaly bět Łźinněmi katalyz tory f zov‚ho pýenosu pýi enantioselektivnˇ MichaelovŘ adici. Po odborn‚ str nce jsou zˇs (cs)
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