About: Electrochemistry of nano-structures at heterogeneous interfaces: formation, properties and electron transfer reactions.     Goto   Sponge   NotDistinct   Permalink

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Description
  • Research of redox reaction of organic and organometallic compounds that form isolated and organized structures at the interface solution-metallic electrode. Formation of inclusion complexes of the type host-guest inside cavities of cyclodextrins. Mechanism of redox activation inside cavities of cyclodextrins. Mechanism of electron transfer by means of through bonds and through space. Electronic communication of redox centers. Mechanism of nucleation and growth of monomolecular and multilayer films. In situ detection of redox intermediates. Electrode impedance for analysis of film formation. Quantum chemical interpretation of redox reactions. (en)
  • Výzkum redox reakcí organických a organometalických sloučenin, které tvoří izolované a organizované struktůry na mezifází roztok-kovová elektroda. Tvorba inklusních komplexů typu host-hostitel uvnitř kavity cyklodextrinů Mechanismus redox aktivace uvnitř kavity cyklodextrinů. Mechanismus přenosu elektronu přes vazvy a prostorem. Elektronická komunikace mezi redox centry. Mechanismus nukleace a růstu monomolekulárních filmů a multivrstev. In-situ detekce redox intermediátů. Elektrodová impedance pro analysu tvorby filmů. Kvantově-chemická interpretace redox realcí.
Title
  • Electrochemistry of nano-structures at heterogeneous interfaces: formation, properties and electron transfer reactions. (en)
  • Elektrochemie nano-struktur na heterogenních mezifázích: tvorba, vlastnosti a reakce přenosu elektronu.
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  • OC D15.10
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  • organized mono-layers, electron transfer, heterogeneous recognition, redox catalysis, complexes, electrochemistry (en)
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  • Charakterizována rozsáhlá řada nových koordinačních sloučenin platinových kovů (cs)
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  • complexes
  • electron transfer
  • heterogeneous recognition
  • redox catalysis
  • organized mono-layers
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